Annual Report of the Great Plains/Rocky
Mountain Hazardous Substance Research Center

December 1996



Research Project Description

May 18, 1995 - September 30, 1996


Acid Producing Metalliferous Waste Reclamation by Material Reprocessing and Vegetative Stabilization
F.F. Munshower, Montana State University

Goals: This project will attempt to demonstrate an alternative, cost-effective, permanent mine tailing reclamation methodology through the marriage of mineral processing and land reclamation techniques. The approach to be used, Clean Tailing Reclamation (CTR), utilizes potentially field deployable mineral separation technologies to remove dense sulfide minerals from tailing material by gravimetric separation, followed by vegetative stabilization of the cleaned tailing material with native plants. CTR will allow for removal of environmental contaminants and acid-forming materials.

Rationale: Mine waste is a widespread and pervasive problem in EPA Regions VII and VIII. Historical mining activity has contaminated many thousands of acres of soil by uncontrolled waste disposal practices resulting in resource degradation that will cost billions of dollars to remediate. One of the principal problems associated with reclamation of hardrock mine sites is tailing reclamation. Tailing materials cover tens of thousands of acres of land in the region pair. This research specifically compliments research being conducted in Anaconda, Montana, on tailing reclamation and will provide comparisons on the relative strength of this technology, through plant performance, geochemical distribution of contaminants, and cost of implementation. Upon completion of this research, the findings will be useful to Superfund Managers and Potentially Responsible Party decision makers and to operational mines and regulators.

Approach: Research will be implemented at Montana State University. Outside expertise will be solicited from other experts in mineral separation in conjunction with the use of experimental equipment housed at Butte, Montana. Contract laboratories will be solicited and appropriate sample analyses will be submitted for analysis. Sample material used in research will be collected from three locations in coordination with regulatory personnel. Representative samples of tailings materials will be collected from each of the three locations and chemically characterized to identify the elemental and mineralogical distribution of the heavy metal and acid generating contaminants. Subsequent to sample characterization, mineralogical separation of the dense sulfide minerals will be performed using gravimetric techniques. For bench-scale work, mineral separation technologies considered will include technologies developed through the Superfund Innovative Technology Evaluation (SITE) Program. Following tailing material reprocessing activity, subsamples will be chemically characterized to determine the efficacy of the reprocessing/tailing cleaning technologies. Greenhouse studies will be implemented in the cleaned tailing material to compare performance of the cleaned tailing material with conventional reclamation approaches. The native grass species selected for use are Red top (Agrostis alba) and Basin wildrye (Leymus cinereus).

Status: During the first phase of this study, significant effort was expended to collect samples and initiate the project. Three tailing materials were collected, transported to the laboratory and characterization completed. Bench scale and subsequent pilot scale separation of sulfides from silicates in tailings was performed. Soluble chemistry evaluation of various treatments was initiated, as was literature-review activity. Much of the research conducted during the early phase of the project has been completed. Samples were submitted for acid-base account analysis for characterization of the acid generating potential of all three trailing materials -- both before and after reprocessing. Metal analysis of the initial tailing material, high-grade concentrate and cleaned tailing material has been performed. The greenhouse study began May 31, 1996. It will be completed in the near future and data collected will be summarized and evaluated. The soluble chemistry study is complete and data reduction efforts have been initiated. A technology transfer seminar was hosted with participants from industry and government attending. Further inquiry of mineral separation effectiveness is planned. The potential for metal recovery and reuse will also be evaluated upon receipt of the final metal analyses, which are underway. Field visits will be conducted to evaluate the potential for conducting field scale tailing cleaning in a mining environment. Data summary, interpretation and write-up will follow completion of data collection. This project is in its second year.

Clients/Users: This research will be of interest to those in the mining industry and regulatory agencies.

Key words: vegetation, reclamation, metallic minerals, mining, tailings.

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